Publications

Please see the link "publication" to open the pdf file of the list of publications. The pdf contains active links to the deposited individual publications.

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Solid-Solution Mixed-Linker-Synthesis of Isoreticular Al-based MOFs for an Easy Hydrophilicity Tuning in Water-Sorption Heat Transformations; Humidity Control;

C. Schlüsener, M. Xhinovci, S.-J. Ernst, A. Schmitz, N. Tannert, C. Janiak,

Chem. Mater. 2019, 31, 4051-4062.

undefined[495.pdf-Datei]  https://pubs.acs.org/doi/10.1021/acs.chemmater.9b00617

We use and demonstrate here the "solid-solution" mixed-linker approach (defined as variation of two linker proportions) as an easy and inexpensive way to fine-tune the hydrophilicity properties of isoreticular MOFs. The water uptake region was easily shifted in between the limits set by the two single-ligand MOFs.
Dalton Transactions
Water Vapor Single-Gas Selectivity via Flexibility of Three Potential Materials for Autonomous Indoor Humidity Control;

P. Kenfack Tsobnang, E. Hastürk, D. Fröhlich, E. Wenger, P. Durand, J. Lambi Ngolui, C. Lecomte, C. Janiak,

Cryst. Growth Des. 2019, 19, 2869-2880. undefined[488pdf-file]  https://doi.org/10.1021/acs.cgd.9b00097

The new isostructural porous supramolecular materials {[Cu2(amp)4Cl][M(C2O4)3]·6H2O}n show good potential to be used for automatic indoor control in the range of 15 to 25% r.H. recommended for many activities.
Aggregation control of Ru and Ir nanoparticles by tunable aryl alkyl imidazolium ionic liquids;

L. Schmolke, S. Lerch, M. Bülow, M. Siebels, A. Schmitz, J. Thomas, G. Dehm, C. Held, T. Strassner, C. Janiak,

Nanoscale 2019, 11, 4073–4082. [485pdf-file]  http://doi.org/10.1039/C8NR10286D

Small change - large effect: An added para-methyl group on the aryl ring in the 1-aryl-3-alkyl-imidazolium motif of TAAILs leads to well-separated metal nanoparticles.
Assessing Guest Molecule Diffusion in Heterogeneous Powder Samples of Metal-Organic Frameworks through PFG-NMR

R. Thoma, J. Kärger,* N. de Sousa Amadeu, S. Nießing, C. Janiak*

Chem. Eur. J. 2017, 23, 13000-13005.


http://dx.doi.org/10.1002/chem.201702586

undefined423 Thoma CEJ17 guest molecule diff in MOFs through PFG-NMR.pdf

 

Section Head

Prof. Dr. Christoph Janiak

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Building: 26.43
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Fax +49 211 81-11611580

Secretariat

Jutta Bourgeois

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40225 Düsseldorf
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Fax +49 211 81-11611580
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